Chapter 12: Q1P (page 595)
Complete the following conversion table:
4000 | 1800 | 1670 | 1620 | 400 | ||||
2.50 | 3.40 | 3.13 | 4.87 | 25.0 |
Short Answer
4000 | 2941.17 | 3095.97 | 2053.38 | 1800 | 1670 | 1620 | 400 | |
2.50 | 3.40 | 3.13 | 4.87 | 5.55 | 5.98 | 6.17 | 25.0 |
Chapter 12: Q1P (page 595)
Complete the following conversion table:
4000 | 1800 | 1670 | 1620 | 400 | ||||
2.50 | 3.40 | 3.13 | 4.87 | 25.0 |
4000 | 2941.17 | 3095.97 | 2053.38 | 1800 | 1670 | 1620 | 400 | |
2.50 | 3.40 | 3.13 | 4.87 | 5.55 | 5.98 | 6.17 | 25.0 |
All the tools & learning materials you need for study success - in one app.
Get started for freeQuestion: Consider the following four structures, followed by mass spectral data. Match each structure with its characteristic molecular ion or fragment. In each case, give a likely structure of the ion responsible for the base peak
(a) base peak at 105
(b) base peak at 72
(c) doublet at 198 and 200, base peak at 91
(d) base peak at 91, large peak at 43
The ultimate test of fluency in MS and IR is whether you can determine a moderately complex structure from just the MS and the IR, with no additional information. The IR and MS of a compound are shown below. Use everything you know about IR and MS, plus reasoning and intuition, to determine a likely structure. Then show how your proposed structure is consistent with these spectra.
Show the fragmentations that give rise to the peaks at m/z 43, 57, and 85 in the mass spectrum of 2,4-dimethylpentane (Figure 12-17).
Chapter-9 covered a synthesis of alkynes by a double dehydrohalogenation of dihalides. A student tried to convert trans-2,5-dimethylhex-3-yne by adding bromine across the double bond and then doing a double elimination. The infrared and mass spectra of the major product are shown here.
Predict the masses and the structures of the most abundant fragments observed in the mass spectra of the following compounds
a. 2-methylpentane
b. 3-methylhex-2-ene
c. 4-methylpentane-2-ol
d. 2-methyl-1-phenylpropane
e. Cyclohexylisopropy; ether [cyclohexyl--O-CH(CH3)2 ]
f. CH3CH2CH2NHC(CH3)2
g.
h.3-bromo-2-methylpentane
What do you think about this solution?
We value your feedback to improve our textbook solutions.