Question:Spectra are given for three compounds. Each compound has one or more of the following functional groups: alcohol, amine, ketone, aldehyde, and carboxylic acid. Determine the functional group(s) in each compound, and assign the major peaks above 1600cm-1.

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01

IR spectroscopy

IR spectroscopy helps detect the functional groups present in the given organic compound. Observe closely the peaks that are obtained in the IR spectrum. Each functional group has a characteristic absorption in IR spectroscopy.

02

Subpart (a)

If the given spectrum is observed, the peaks are observed at represents the 1660cm-1 stretch.

A medium peak at3360cm-1-3200cm-1 indicates the N-H stretch.

The peaks betweenrole="math" localid="1660720065115" 3000cm-1-2840cm-1 indicates the presence of C-H stretch.

Hence, the peaks role="math" localid="1660720014870" 1600cm-1above are N-H stretch, C-H stretch, and C=O stretch.

03

Subpart (b)

If the given spectrum is observed, a broad peak is observed between 3300cm-1-2500cm-1, representing the O-H stretch. The peaks between 3000cm-1-2840cm-1indicates the presence of C-H stretch.

The peak at 31711cm-1indicates the in carboxylic acid.

Thus, the peaks above1600cm-1 are O-H stretch, C-H stretch, and C=O stretch.

04

 Step 4: Subpart (c)

If the given spectrum is observed, a broad peak is observed between3500cm-1-3300cm-1 , representing the O-H stretch. The peaks between3000cm-1-2840cm-1 indicates the presence of C-H stretch.

Thus, the peaks above are O-H stretch, and C-H stretch.

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Most popular questions from this chapter

For each spectrum, interpret all the significant streching frequencies above 1580 cm-10

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