Draw the structures of the following derivatives.

(a) the 2,4-dinitrophenylhydrazone of acetone

(b) the semicarbazone of cyclopentanone

(c) cyclcobuanone oxime

(d) the ethylene acetal of hexan-2-one

(e) acetaldehyde diethyl acetal

(f) the ethyl hemiacetal of acetaldehyde

(g) the (Z) isomer of the ethyl imine of propiophenone

(h) the hemiacetal form of 6-hydroxyhexanal

Short Answer

Expert verified

a.

b.

c.

d.

e.

f.

g.

h.

Step by step solution

01

Hydrazone

A compound containing C=NNH2group, formed by the reaction of a ketone or an aldehyde with hydrazine is known as hydrazone.

02

Semicarbazone

A compound containing C=NNHCONH2group, formed by the reaction of a ketone or an aldehyde with semicarbazide is known as semicarbazone.

03

Oxime

A compound containingC=NOH group, formed by the reaction of a ketone or an aldehyde with hydroxylamine is known as oxime.

04

Imine

Ammonia or primary amine under proper conditions reacts with a ketone or an aldehyde to form an imine.

05

Acetal

It is a derivative of an aldehyde or a ketone having two alkoxy groups in place of the carbonyl group.

06

Hemiacetal

It is a derivative of an aldehyde or a ketone with just one alkoxy group and one hydroxy group on the carbonyl carbon atom.

07

Ethylene acetal

A cyclic acetal where ethylene glycol is used as the alcohol.

08

Drawing the structures of the derivatives

a.

b.

c.

d.

e.

f.

g.

h.

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