Chapter 25: Q-25-2P (page 1305)
Give an equation for the complete hydrogenation of trilinolein using an excess of hydrogen. Name the product and predict approximate melting points for the starting material and the product.
Chapter 25: Q-25-2P (page 1305)
Give an equation for the complete hydrogenation of trilinolein using an excess of hydrogen. Name the product and predict approximate melting points for the starting material and the product.
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Get started for freePhospholipids undergo saponification much like triglycerides. Draw the structure of a phospholipid meeting the following criteria. Then draw the products that would result from its saponification.
(a) a cephalin containing stearic acid and oleic acid
(b) a lecithin containing palmitic acid.
When an extract of parsley seed is saponified and acidified, one of the fatty acids isolated is petroselenic acid, formula C18H34O2. Hydrogenation of petroselenic acid gives pure stearic acid. When petroselenic acid is treated with warm potassium permanganate followed by acidification, the only organic products are dodecanoic acid and adipic acid. The NMR spectrum shows absorptions of vinyl protons split by coupling constants of 7 Hz and 10 Hz. Propose a structure for petroselenic acid, and show how your structure is consistent with these observations.
Question: Trimyristin, a solid fat present in nutmeg, is hydrolyzed to give one equivalent of glyceroland three equivalents of myristic acid. Give the structure of trimyristin.
Show how you would convert linoleic acid to the following fatty acid derivatives.
Draw the structure of an optically active triglyceride containing one equivalent of stearic acid and two equivalents of oleic acid. Draw the products expected when this triglyceride reacts with the following reagents. In each case, predict whether the products will be optically active.
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