Chapter 13: Q3P (page 658)
Determine the number of different kinds of protons in each compounds
- 1-bromopropane (b) 2-bromopropane
- 2,2-dimethylpropane (d) 2,2-dimethylpentane
- (e) 1-chloro-4-methylbenzene (f) 1-chloro-2-methylbenzene
Chapter 13: Q3P (page 658)
Determine the number of different kinds of protons in each compounds
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Get started for freeQuestion:In a 300-MHz spectrometer, the protons in bromomethane absorb at a position 660 Hz downfield from TMS.
(a) What is the chemical shift of these protons?
(b) What is the chemical shift of the bromomethane protons in a 60-MHz spectrometer?
(c) How many hertz downfield from TMS would they absorb at 60 MHz?
Each of these four structures has molecular formula . Match the structure with its characteristic proton NMR signals. (Not all of the signals are listed in each case.)
Predict the chemical shifts of the protons in the following compounds
Sets of spectra are given for two compounds. For each set,
(1) Look at each spectrum individually and list the structural characteristics you can determine from that spectrum.
(2) Look ar the set of spectraas a group and purpose a tentative structure.
(3) Verify that your proposed structure accounts for the major features of each spectrum. The solution for compound 1 is given after the problem but go as far as you can before looking at the solution.
Phenyl Grignard reagent adds to 2-methylpropanal to give the secondary alcohol shown. The proton NMR of 2-methylpropanal shows the two methyl groups as equivalent (one doublet at δ 1.1), yet the product alcohol, a racemic mixture, shows two different 3H doublets, one at δ 0.75 and one around δ 1.0
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