Draw the NMR spectra you expect for the following complexes.

Protocol of the H-1 NMR Prediction (Lib=SU Solvent=DMSO 300 MHz):

The nmr values of each compounds of this compounds are given here.

Node Shift Base + Inc. (ppm rel. to TMS)

CH 7.24 7.26 1-benzene

0.04 1 -C=C

-0.06 general corrections

CH 7.24 7.26 1-benzene

0.04 1 –C=C

-0.06 general corrections

CH 7.24 7.26 1-benzene

-0.05 1 -C=C

0.03 general corrections

CH 7.24 7.26 1-benzene

-0.05 1 -C=C

0.03 general corrections

CH 7.33 7.26 1-benzene

-0.12 1 -C=C

0.19 general corrections

CH3 0.82 0.86 methyl

0.02 1 beta -C=C

0.10 2 beta -C

-0.16 general corrections

CH3 0.82 0.86 methyl

0.02 1 beta -C=C

0.10 2 beta -C

-0.16 general corrections

CH3 0.82 0.86 methyl

0.02 1 beta -C=C

0.10 2 beta -C

-0.16 general corrections

H 6.44 5.25 1-ethylene

1.38 1 -1:C*C*C*C*C*C*1 gem

-0.22 1 -C cis

0.03 general corrections

H 6.06 5.25 1-ethylene

0.36 1 -1:C*C*C*C*C*C*1 cis

0.45 1 -C ge

Protocol of the H-1 NMR Prediction (Lib=SU Solvent=DMSO 300 MHz):

The nmr values of each compounds of this compounds are given here.

Node Shift Base + Inc. Comment (ppm rel. to TMS)

CH3 3.51 0.86 methyl

2.64 1 alpha -O-C=C

0.01 general corrections

CH3 2.05 0.86 methyl

0.85 1 alpha -C=C

0.34 general corrections

H 4.67 5.25 1-ethylene

0.18 1 -Cl cis

-1.21 1 -O-C trans

0.45 1 -C gem

1H NMR Coupling Constant Prediction

shift atom index coupling partner, constant and vector

3.51 7

2.05 3

5 6.4 H-CH2-C(sp2)-H

Protocol of the H-1 NMR Prediction (Lib=SU Solvent=DMSO 300 MHz):

The nmr values of each compounds of this compounds are given here.

Node Shift Base + Inc. Comment (ppm rel. to TMS)

CH2 4.06 1.37 methylene

0.00 1 alpha -C

2.82 1 alpha -OC(=O)C=C

-0.13 general corrections

CH3 3.80 0.86 methyl

2.64 1 alpha -O-C=C

0.30 general corrections

CH3 1.21 0.86 methyl

0.44 1 beta -OC(=O)-C=C

-0.09 general corrections

H 6.93 5.25 1-ethylene

1.22 1 -O-C gem

0.46 1 -C(=O)O-R trans

H 4.82 5.25 1-ethylene

-1.21 1 -O-C trans

0.78 1 -C(=O)O-R gem

Protocol of the H-1 NMR Prediction (Lib=SU Solvent=DMSO 300 MHz):

The nmr values of each compounds of this compounds are given here.

Node Shift Base + Inc. Comment (ppm rel. to TMS)

OH 12.71 11.00 carboxylic acid

1.00 1 -C*R

0.71 general corrections

CH3 2.41 0.86 methyl

1.40 1 alpha -1:C*C*C*C*C*C*1

0.15 general corrections

H 8.04 7.26 1-benzene

0.87 1 -C(=O)O

-0.05 1 -C

-0.04 general corrections

H 7.30 7.26 1-benzene

0.21 1 -C(=O)O

-0.12 1 -C

-0.05 general corrections

H 8.04 7.26 1-benzene

0.87 1 -C(=O)O

-0.05 1 -C

-0.04 general corrections

H 7.30 7.26 1-benzene

0.21 1 -C(=O)O

-0.12 1 -C

-0.05 general corrections