Chapter 11: Q31P (page 573)
Show the alcohol and the acid chloride that combine to make the following esters.
(a)
(b)
(c)
(d)
Short Answer
(a)
(b)
(c)
(d)
Chapter 11: Q31P (page 573)
Show the alcohol and the acid chloride that combine to make the following esters.
(a)
(b)
(c)
(d)
(a)
(b)
(c)
(d)
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Get started for freeClassify each reaction as an oxidation, a reduction, or neither.
Give the structures of the products you would expect when each alcohol reacts with
(1) HCl, ZnCl2; (2) HBr; (3) PBr3; (4) P/I2; and (5) SOCl2.
(a) butan-1-ol (b) 2-methylbutan-2-ol
(c) 2,2-dimethylbutan-1-ol (d) cis-3-methylcyclopentanol
Suggest the most appropriate method for each of the following laboratory syntheses. In each case, suggest both a chromium reagent and a chromium-free reagent
(a) butan - 1 - ol → butanal, CH3CH2CH2CHO
(b) but - 2 - en - 1 - ol → but - 2 - enoic acid, CH3CH = CHCOOH
(c) butan - 2 - ol → butan - 2 - one, CH3COCH2CH3
(d) cyclopentanol → 1 - cyclopentylpropan - 1 - ol (twosteps)
(e) cyclopentyclohexanol → 2 - methylcyclohexanone (several steps)
(f) 1 - methylcyclohexanol → 2 - methylcyclohexanone (several steps)
Unlike ethylene glycol, propylene glycol (propane-1, 2-diol) is non toxic because it oxidizes to a common metabolic intermediate. Give the structures of the biological oxidation products of propylene glycol.
Write balanced equations for the three preceding reactions.
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