Log out Go to App
Go to App

Learning Materials

Features

Discover

Chapter 17: Q29P (page 885)

What products would you expect from the following Suzuki coupling reactions?

Short Answer

Expert verified

⦁ The product expected from the first reaction:

⦁ The product expected from the second reaction:

Step by step solution

01

Suzuki Reaction

Suzuki reaction is a type of metal catalyst reaction in which palladium metal catalyst has been used to do the coupling reaction.

The main compound used in this reaction is the base with hydroxide or carbonate ions. The other necessary reactant used in this reaction is an organoboron compound.

02

Subpart (a) The product expected from the given coupling Suzuki Reaction.

Ary halide reacting 1-Bromo-4-(tert-butyl)benzene with aryl boronic acid with the help of palladium-catalyzed substitution couples the carbon of two aryl rings to form the 4’-(tert-butyl)-a 2-methyl-1,1’-biphenyl product, which is a conjugated biaryl system.

Formation of 4’-(tert-butyl)-a 2-methyl-1,1’-biphenyl

03

Subpart (b) The product expected from the given coupling Suzuki Reaction.

Ary halide (Bromobenzene) reacts with aryl boronate ester with the help of palladium-catalyzed substitution reaction that couples the two aryl rings to form the product 3-phenyl pyridine, which is a conjugated biaryl system.

Formation of 3- phenyl pyridine

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Start your free trial

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

In Chapter 14, we saw that Agent Orange contains (2,4,5-trichlorophenoxy) acetic acid, called 2,4,5-T. This compound is synthesized by the partial reaction of 1,2,4,5-tetrachlorobenzene with sodium hydroxide, followed by a reaction with sodium chloroacetate, ClCH2CO2Na.

(a) Draw the structures of these compounds, and write equations for these reactions.

(b) One of the impurities in the Agent Orange used in Vietnam was 2,3,7,8-tetrachlorodibenzodioxin (2,3,7,8-TCDD), often incorrectly called “dioxin.” Propose a mechanism to show how 2,3,7,8-TCDD is formed in the synthesis of 2,4,5-T.

(c) Show how the TCDD contamination might be eliminated, both after the first step and on completion of the synthesis

Predict the major products when the following compounds are irradiated by light and treated with (1) 1 equivalent of Br2 and (2) excess Br2.

(a) isopropylbenzene

(b) tetralin

What products would you expect from the following reactions?

Show how you would synthesize the following compounds, using the indicated starting materials.

(a) 3-phenylbutan-1-ol from styrene

Show how you would use Suzuki reactions to synthesize these products from the indicated starting materials. You may use any additional reagents you need.
See all solutions

Recommended explanations on Chemistry Textbooks

Physical Chemistry

Read Explanation

Chemistry Branches

Read Explanation

Making Measurements

Read Explanation

Chemical Analysis

Read Explanation

The Earths Atmosphere

Read Explanation

Kinetics

Read Explanation
View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free