Chapter 3: 44P (page 190)
Use a Newman projection about the indicated bond to draw the most stable conformer for each compound.
(a)
(b)
Chapter 3: 44P (page 190)
Use a Newman projection about the indicated bond to draw the most stable conformer for each compound.
(a)
(b)
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Get started for freeQuestion: Draw Newman projections along the C3-C4bond to show the most stable and least stable conformations of 3 ethyl-2,4demethylheptane.
Table 3-6 shows that the axial-equatorial energy difference for methyl, ethyl, and isopropyl groups increases gradually: 7.6, 7.9 and 8.8 kJ/mol (1.8, 1.9, and 2.1 kcal/mol). The tert-butyl group jumps to an energy difference of 23 kJ/mol (5.4 kcal/mol), over twice the value for the isopropyl group. Draw pictures of the axial conformations of isopropylcyclohexane and tert-butylcyclohexane and explain why the tert-butyl substituent experiences such a large increase in axial energy over the isopropyl group.
trans - 1,2 - dimethylcyclobutane is more stable than cis - 1,2 -dimethylcyclobutane, but cis - 1,3 - dimethylcyclobutane is more stable than trans - 1,3 - dimethylcyclobutane. Use drawings to explain these observations.
Question: Write the structure for the following compounds.
(a) 3-ethyl-4-methylhexane
(b) 3-ethyl-5-isobutyl-3-methylnonane
(c) 4-tert-butyl-2-methylheptane
(d) 5-isopropyl-3,3,4-trimethyloctane
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