Chapter 3: Q18P (page 168)
Give IUPAC names for the following cycloalkanes.
(a)
(b)
(c)
Short Answer
(a)cis-1-ethyl-3-methylcyclobutane
(b)trans-1-tert-butyl-3-ethyl cyclohexane
(c)trans-1,2-dimethyl cyclopropane
Chapter 3: Q18P (page 168)
Give IUPAC names for the following cycloalkanes.
(a)
(b)
(c)
(a)cis-1-ethyl-3-methylcyclobutane
(b)trans-1-tert-butyl-3-ethyl cyclohexane
(c)trans-1,2-dimethyl cyclopropane
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Get started for freeQuestion: Draw a graph, similar to Figure 3-11, of the torsional energy of as it rotates about the bond.
Construct a graph, similar to Figure 3-11, of the torsional energy of along the.Placein front, represented by three bonds coming together in a Y shape, andin back, represented by a circle with three bonds pointing out from it. Define the dihedral angle as the angle between the methyl group on the front carbon and ethyl group on the back carbon. Begin your graph at thedihedral angle and begin to turn the front carbon. Show the Newman projection and the approximate energy at eachof rotation. Indicate which conformations are the most stable (lowest energy) and the least stable (highest energy).
Use your results from Problem 3-27 to complete the following table. Each entry shows the positions of two groups arranged as shown. For example, two groups that are trans on adjacent carbons must be equatorialor both axial.
Draw the two chair conformations of each compound, and label the substituents as axial and equatorial. In each case, determine which conformation is more stable.
(a)
(b)
(c)
(d)
(e)
(f)
Using what you know about the conformational energetics of substituted cyclohexanes, predict which of the two isomers is more stable. Explain your reasoning.
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