Chapter 10: Q12P (page 513)
Question: Predict the products of the following reactions.
(a)
(b)
(c)
(d)
Short Answer
Answer
(a)
(b)
(c)
(d)
(e)
Chapter 10: Q12P (page 513)
Question: Predict the products of the following reactions.
(a)
(b)
(c)
(d)
Answer
(a)
(b)
(c)
(d)
(e)
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Get started for freeDetermine the structures of compounds A through G, including stereochemistry where appropriate.
A nitro group (-NO2) effectively stabilizes a negative charge on an adjacent carbon atom through resonance:
Two of the following nitrophenols are much more acidic than phenol itself. The third compound is only slightly more acidic than phenol. Use resonance structures of the appropriate phenoxide ions to show why two of these anions should be unusually stable.
Compounds containing deuterium (D =2H) are useful for kinetic studies and metabolic studies with new pharmaceuticals. One way to introduce deuterium is by using the reagent LiAID4, equivalent in reactivity to LiAID4. Show how to make these deuterium-labeled compounds, using LiAID4and D2Oas your sources of deuterium, and any non-deuterated starting materials you wish.
(a) CH3CHDOH (b) CH3CD2OH (c) CH3CD2OD
Show how you would accomplish the following transformations. You may use any additional reagents you need.
Give a systematic (IUPAC) name for each diol.
a.
b.
c.
d.
e.
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