Which of the following are not acids?

CH3COOH CO2 HNO2 HCOOH CCl4

Short Answer

Expert verified

CCl4 is not acid as it doesn’t have any lone pair to accept electrons (Lewis acid) or doesn’t have any dissociative bond from which it can generate proton in solution (Bronsted acid).

Step by step solution

01

Define acidity 

Acidity is defined as the proton releasing ability in a solution of a compound. The more is the ability of releasing H+, the more it shows acidic character. The main driving force of releasing H+ is the stabilisation of the conjugate base.

02

Determination of acidity of the compounds

Among all the compounds given above, CCl4 is not an acid because it doesn’t have any acidic hydrogen to release or any lone pair to accept electrons.

03

Reason behind acidity of all compounds

In the 1st compound, CH3COOH is acidic as it produces H+ ion in the solution maintaining the equilibrium.

For the CO2 molecule, it is a Lewis acid which reacts with H2O to produce carbonic acid in the solution.

For HNO2 molecule, the compound is acidic as it generates H+ in the solution and a NO2- ion which is stabilised through resonance.

For HCOOH, it is a strong acid and it generates H+ ion and the conjugate base becomes highly stabilised through resonance.

In case of CCl4, there is no lone pair to accept H+ or bond to generate H+ in solution. Moreover, the C-Cl bond is more convalent than ionic. So CCl4 doesn’t show acidity.

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