Chapter 5: Q 10TP (page 190)
Use what the curved arrows tell you about electron movement to determine the product(s) of each reaction step.
Chapter 5: Q 10TP (page 190)
Use what the curved arrows tell you about electron movement to determine the product(s) of each reaction step.
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Get started for freeQuestion: a. Which of the monosubstituted cyclohexanes in Table 3.9 on p. 128 has a negative ∆G° for the conversion of an axial-substituted chair conformer to an equatorial-substituted chair conformer?
b.Which monosubstituted cyclohexane has the most negative ∆G° for this conversion?
c. Which monosubstituted cyclohexane has the greatest preference for an equatorial position?
d. Calculate ∆G° for the conversion of “axial” methylcyclohexane to “equatorial” methylcyclohexane at 25 °C.
Squalene, a hydrocarbon with the molecular formula C30H50, is obtained from shark liver. (Squalus is Latin for “shark.”) If squalene is an acyclic compound, how many π bonds does it have?
a. What is the equilibrium constant for a reaction that is carried out at 25°C (298 K) with ΔH° = 20 kcal/mol and ΔS° = 5.0 x 10-2 kcal mol-1 K-1?
b. What is the equilibrium constant for the same reaction carried out at 125°C?
From the following rate constants, determined at five temperatures, calculate the experimental energy of activation and ΔG±,ΔH±,andΔS±for the reaction at 30°C:
Draw curved arrows to show the flow of electrons responsible for the conversion of the reactants to products
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