Chapter 5: Q16 P (page 201)
Draw the products that would be obtained by following the incorrect arrows in the box entitled “A Few Words about Curved Arrows” and explain what is wrong with the structures you obtain.
Short Answer
Nothing
Chapter 5: Q16 P (page 201)
Draw the products that would be obtained by following the incorrect arrows in the box entitled “A Few Words about Curved Arrows” and explain what is wrong with the structures you obtain.
Nothing
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Get started for freeQuestion: a. How many vinylic hydrogens does cyclopentene have?
b. How many allylic hydrogens does it have?
Question: Which of the following are electrophiles, and which are nucleophiles?
For a reaction carried out at 25°C with an equilibrium constant of 1 × 10−3, in order to increase the equilibrium constant by a factor of 10:
a. How much must ΔG° change?
b. How much must ΔH° change if ΔS° = 0 kcal mol-1 K-1?
c. How much must ΔS° change if ΔH° = 0 kcal mol-1?
a. For a reaction with ∆H° = -12 kcal/mol and ∆S° = 0.01kcal mol-1 K-1, calculate the ∆G° and the equilibrium constant at: 1. 30 °C and 2. 150 °C.
b. How does ∆G° change as T increases?
c. How does Keq change as T increases?
a. What is the equilibrium constant for a reaction that is carried out at 25°C (298 K) with ΔH° = 20 kcal/mol and ΔS° = 5.0 x 10-2 kcal mol-1 K-1?
b. What is the equilibrium constant for the same reaction carried out at 125°C?
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