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Chapter 8: Q37 P (page 355)

What are the major 1,2- and 1,4-addition products of the following reactions? For each reaction, indicate the kinetic and the thermodynamic product.

Short Answer

Expert verified

a.

b.

Step by step solution

01

How reaction proceed

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b)

02

Final answer

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b)

1,2-product is always the Kinetic product and the thermodynamic product is the product with the most highly substituted double bond.

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Most popular questions from this chapter

Which carbocation in each pair is more stable?

b. CH3OC+H2 or CH3NHC+H2

Explain why the following compounds are not optically active:

a. the product obtained from the reaction of 1,3-butadiene with cis-1,2-dichloroethene

b. the product obtained from the reaction of 1,3-butadiene with trans-1,2-dichloroethene

The following equilibrium is driven to the right if the reaction is carried out in the presence of maleic anhydride (see Problem 106). What is the function of maleic anhydride?

Draw the major products obtained from the reaction of one equivalent of HBr with the following compounds. For each reaction, indicate the kinetic product and the thermodynamic product.

a. The following compounds have the same molecular formula as benzene. How many monosubstituted products would each have?

1.HC≡CC≡CCH2CH3 2. CH2≡CHC≡CCH≡CH2

b. How many disubstituted products would each of the preceding compounds have? (Do not include stereoisomers.)

c. How many disubstituted products would each of the compounds have if stereoisomers are included?
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