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Chapter 8: Q40 P (page 358)

What is the major product when the methoxy substituent in the preceding reaction is bonded to C-2 of thediene rather than to C-1?

Short Answer

Expert verified

The major product changing the methoxy group from C-1 to C-2 of diene is

Step by step solution

01

Definition of Diels-Alder reaction

Diels Alder reaction is a pericyclic reaction where a diene and dienophile reacts to form a cyclic entity. This reaction is a reversible reaction. At high temperature, the cyclic compound breaks to get back the reactants,

02

Reaction with different methoxy connectivity

Methoxy is an electron donating group. The partial charge distribution around diene will change if position of methoxy is changed from C-1 to C-2.

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Most popular questions from this chapter

Which of the following are aromatic?

Explain why the pka of p-nitrophenol is 7.14, whereas the pka of m-nitrophenol is 8.39.

a.What is the value of nin Hückel’s rule when a compound has nine pairs of π electrons?

b. Is such a compound aromatic?

Which compound is the strongest base?

On a single graph, draw the reaction coordinate diagram for the addition of one equivalent of HBr to 2 methyl-1,3-pentadiene and for the addition of one equivalent of HBr to 2-methyl-1,4-pentadiene. Which reaction is faster?
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