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Chapter 8: Q42 P (page 360)

What two products are formed from each of the following reactions?

Short Answer

Expert verified

The following products are given below following the Diels-Alder reaction.

Step by step solution

01

Definition of Diels-Alder reaction

Diels Alder reaction is a pericyclic reaction where a diene and dienophile reacts to form a cyclic entity. This reaction is a reversible reaction. At high temperature, the cyclic compound breaks to get back the reactants,

02

Given quantities

The following products are given below,

a)

b) The reaction in case of b is given below,

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Most popular questions from this chapter

As many as 18 different Diels–Alder products can be obtained by heating a mixture of 1,3-butadiene and 2-methyl-1,3-butadiene. Identify the products.

Identify the product of the following reaction. (Hint:It has a fused bicyclic ring.)

a. When HBr adds to a conjugated diene, what is the rate-determining step?

b. When HBr adds to a conjugated diene, what is the product-determining step?

The A ring ( Section 3.16 ) of cortisone, a steroid, is formed by a Diels–Alder reaction using the two reactants shown here. What is the product of this reaction?

The C ring of estrone (a steroid) is formed by a Diels–Alder reaction using the tworeactants shown here. What is the product of this reaction?

Answer the following questions for the molecular orbitals (MOs) of 1,3,5,7-octatetraene:

a. How many MOs does the compound have?

b. Which are the bonding MOs, and which are the antibonding MOs?

c. Which MOs are symmetric, and which are antisymmetric?

d. Which MO is the HOMO and which is the LUMO in the ground state?

e. Which MO is the HOMO and which is the LUMO in the excited state?

f. What is the relationship between HOMO and LUMO and symmetric and antisymmetric orbitals?

g. How many nodes does the highest-energy MO of 1,3,5,7-octatetraene have between the nuclei?
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