Chapter 8: Q57P (page 369)
What orbitals contain the electrons represented as lone pairs in the structures of quinoline, indole, imidazole, purine, and pyrimidine?
Chapter 8: Q57P (page 369)
What orbitals contain the electrons represented as lone pairs in the structures of quinoline, indole, imidazole, purine, and pyrimidine?
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Between 1865 and 1890, other possible structures were proposed for benzene such as those shown here. Considering what nineteenth-century chemists knew about benzene, which is a better proposal for benzene’s structure, Dewar benzene or Ladenburg benzene? Why?
Why is the delocalization energy of pyrrole (21 kcal/mol) greater than that of furan (16 kcal/mol)?
Which has the greater delocalization energy?
a. When HBr adds to a conjugated diene, what is the rate-determining step?
b. When HBr adds to a conjugated diene, what is the product-determining step?
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