Chapter 14: Q14-65P (page 676)
The 1H NMR spectrum of 2-propane-1-ol is shown here. Indicate the protons in the molecule that are responsible for each of the signals in the spectrum.
Short Answer
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Chapter 14: Q14-65P (page 676)
The 1H NMR spectrum of 2-propane-1-ol is shown here. Indicate the protons in the molecule that are responsible for each of the signals in the spectrum.
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a.
b.
c.
d.
e.
f.
g.
h.
i.
j.
Identify each of the following compounds from its molecular formula and its 13C NMR spectrum:
a.C4H10O
b.C6H12O
Dr. N. M. Arr was called in to help analyze the 1 H NMR spectrum of a mixture of compounds known to contain only C, H, and Br. The mixture showed two singlets-one at 1.8 ppm and the other at 2.7 ppm-with relative integrals of 1: 6, respectively. Dr. Arr determined that the spectrum was that of a mixture of bromomethane and 2-Bromo-2-methylpropane. What was the ratio of bromomethane to 2-Bromo-2-methylpropane in the mixture?
Sketch the following spectra that would be obtained for 2-chloroethnol:
a. The 1H NMR spectrum for an anhydrous sample of the alcohol.
b. The 1H NMR spectrum for a sample of the alcohol that contains a trace amount of acid.
c. The 13C NMR spectrum.
d. The proton-coupled 13C NMR spectrum.
e. The four parts of a DEPT13C NMR spectrum.
How can theirNMR spectra distinguish the following compounds?
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