Chapter 14: Q14-68P (page 677)
Draw a splitting diagram for the Hb proton if Jbc=10 and Jba=5.
Chapter 14: Q14-68P (page 677)
Draw a splitting diagram for the Hb proton if Jbc=10 and Jba=5.
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Get started for freeThe 1H NMR spectra of three isomers with molecular formula C7H14O are shown here. Which isomer produces which spectrum?
a.
b.
c.
A signal is seen at 600 Hz from the TMS signal in an NMR spectrometer with a 300-MHz operating frequency.
a. What is the chemical shift of the signal?
b. What is its chemical shift in an instrument operating at 500 MHz?
c. How many hertz from the TMS signal is the signal in a 500-MHz spectrometer?
Identify the compound with a molecular formula that gives the IR and NMR spectra shown here.
Determine the ratios of the chemically non-equivalent protons in a compound if the steps of the integration curves measure and , from left to right across the spectrum. Draw the structure of a compound whose NMR spectrum would show these integrals in the observed order.
Compound A, with molecular formula C4H9Cl, shows two signals in its 13C NMR spectrum. Compound B, an isomer of compound A, shows foursignals, and in the proton-coupled mode, the signal farthest downfield is a doublet. Identify compounds A and B.
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