Chapter 14: Q14-73P (page 620)
Calculate the amount of energy (in calories) required to flip an 1Hnucleus in an NMR spectrometer that operates at 300 MHz.
Short Answer
The amount of energy required to flip1H nucleus is 475.16 X 10-28
Chapter 14: Q14-73P (page 620)
Calculate the amount of energy (in calories) required to flip an 1Hnucleus in an NMR spectrometer that operates at 300 MHz.
The amount of energy required to flip1H nucleus is 475.16 X 10-28
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Get started for freeThe1H NMR spectra of two compounds, each with the molecular formula C11H16, are shown here. Identify the compounds.
a.
Identify each of the following compounds from the 1H NMR data and molecular formula:
a.C4H8Br2: a 6H singlet at 1.97 ppm
a 2H singlet at 3.89 ppm
b. C8H9Br: a 3H doublet at 2.01 ppm
a 1H quartet at 5.14 ppm
a 5H broad singlet at 7.35 ppm
c. C5H10O2: a 3H triplet at 1.15 ppm
a 3H triplet at 1.25 ppm
a 2H quartet at 2.33 ppm
a 2H quartet at 4.13 ppm
Which underlined proton (or sets of protons) has the greater chemical shift (that is, the higher frequency signal)?
a) For the following compounds which pairs of hydrogen (Ha and Hb) are enantiotopic hydrogens?
b) which pairs are diastereotopic hydrogens?
Identify the compound with a molecular formula that gives the IR and NMR spectra shown here.
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