Chapter 17: Q 6 TP (page 857)
Do a retrosynthetic analysis on each of the following compounds, ending with the given starting materials:
(a)
(b)
Short Answer
Answer:
(a)
(b)
Chapter 17: Q 6 TP (page 857)
Do a retrosynthetic analysis on each of the following compounds, ending with the given starting materials:
(a)
(b)
Answer:
(a)
(b)
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Get started for freeWhich of the following compounds decarboxylates when heated?
Which of the following compounds will decarboxylate when heated?
Explain why a base can remove a proton from the -carbon of N,N-dimethylethanamide but not from the -carbon of either N-methylethanamide or ethanamide.
N,N-dimethylethanamideN-methylethanamide Ethanamide
There are other condensation reactions similar to the aldol and claisen condensations:
a. The Perkin condensation is the condensation of an aromatic aldehyde and acetic anhydride. Draw the product obtained from the following Perkin condensation:
b. What compound is formed if water is added to the product of a Perkin condensation?
c. The Knoevenagel condensation is the condensation of an aldehyde or a ketone that has no alpha- hydrogens and a compound such as diethyl malonate that has an alpha-carbon flanked by two electron- withdrawing groups. Draw the product obtained from the following Knoevenagel condensation:
d. What product is obtained when the product of a Knoevenagel condensation is heated in an aqueous acidic solution?
What compound is formed when a dilute solution of cyclohexanone is shaken with NaOD in for several hours?
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