Chapter 17: Q32P (page 801)
Write the mechanism for the reaction of a 1,7-diester with an alkoxide ion to form a cyclic -keto ester.
Chapter 17: Q32P (page 801)
Write the mechanism for the reaction of a 1,7-diester with an alkoxide ion to form a cyclic -keto ester.
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Get started for freeCompound A with molecular formula C6H10 has two peaks in its 1H NMR spectrum, both of which are singlets (with ratio 9 : 1). Compound Areacts
with an acidic aqueous solution containing mercuric sulfate to form compound B,which gives a positive iodoform test (Problem 58) and has an 1H NMR
spectrum that shows two singlets (with ratio 3 : 1). Identify A and B.
If the preference for formation of a six-membered ring were not so great, what other cyclic product would be formed from the intramolecular aldol addition of
a.2,6-heptanedione? b. 2,8-nonanedione?
Design a synthesis for each of the following compounds using the given starting material:
a)
b)
c)
d)
Show how the following compounds can be prepared from cyclohexanone:
Which of the following compounds will decarboxylate when heated?
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