Chapter 17: Q5TP (page 857)
Describe three ways to synthesize the following compound:
Short Answer
There are three ways for the synthesis of the given molecule is shown below:
Chapter 17: Q5TP (page 857)
Describe three ways to synthesize the following compound:
There are three ways for the synthesis of the given molecule is shown below:
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Get started for freeIn the presence of excess base and excess halogen, a methyl ketone is converted to a carboxylate ion. The reaction is known as the haloform reaction because one of the products is haloform (chloroform, bromoform, or iodoform). Before spectroscopy became a routine analytical tool, the haloform reaction served as a test for methyl ketones: the formation of iodoform, a bright yellow compound, signaled that a methyl ketone was present. Why do only methyl ketones form a haloform?
Explain why the pKaof a hydrogen bonded to the sp3carbon of propene is greater (pKa= 42) than that of any of the carbon acids listed in Table 17.1, but is less than the pKaof an alkane (pKa> 60).
When the enzymatic decarboxylation of acetoacetate is carried out in, all the acetone that is formed contains. What does this tell you about the mechanism of the reaction?
Describe how the following compounds could be prepared from cyclohexanone using an enamine intermediate:
a.
b.
The 1 H NMR chemical shifts of nitromethane, dinitromethane, and trinitromethane are at d 6.10, d 4.33, and d 7.52. Match each chemical shift with the compound. Explain how chemical shift correlates with pKa.
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