Chapter 16: Q 85P (page 797)
Propose a mechanism for each of the following reactions:
Short Answer
Answer:
(a)
(b)
Chapter 16: Q 85P (page 797)
Propose a mechanism for each of the following reactions:
Answer:
(a)
(b)
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Question: Identify A through O:
Imines can exist as stereoisomers. The isomers are named using the E, Z system of nomenclature (Section 4.2). The lone pair has the lowest priority.
Draw the structure of each of the following compounds:
a. the (E)-hydrazone of benzaldehyde
b. the (Z)-oxime of propiophenone
In the presence of an acid catalyst, acetaldehyde forms a trimer known as paraldehyde. Because it induces sleep when it is administered to animals in large doses, paraldehyde is used as a sedative or hypnotic. Propose a mechanism for the formation of paraldehyde.
Question: At what pH should imine formation be carried out if the amine’s protonated form has a Pka value of 9.0?
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