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Chapter 18: Q-18-5P (page 880)

What is the major product of a Friedel-crafts alkylation using the following alkyl chlorides?

a. CH3CH2Cl

b. CH3CH3CH2Cl

c. CH3CH2CH(Cl)CH3

d. (CH3)3CCl

e. (CH2)2CHCH2Cl

f. CH2CHCH2Cl

Short Answer

Expert verified

The answer is,

a.

b.

c.

d.

e.

f.

Step by step solution

01

Friedel Crafts Alkylation Reaction

The Friedel crafts alkylation reaction is the reaction in which an alkyl group gets substituted for a hydrogen atom in the benzene ring. It is an aromatic electrophilic substitution reaction, and the electrophile required is formed from the reaction of an alkyl halide with benzene in the presence of Aluminium chloride.

02

Subpart (a)

The major product of the Friedel crafts alkylation using the given alkyl chloride is shown below.

03

Subpart (b)

The major product of the Friedel crafts alkylation using the given alkyl chloride is shown below.

04

Subpart (c)

The major product of the Friedel crafts alkylation using the given alkyl chloride is shown below.

05

Subpart (d)

The major product of the Friedel crafts alkylation using the given alkyl chloride is shown below.

06

Subpart (e)

The major product of the Friedel crafts alkylation using the given alkyl chloride is shown below.

07

Subpart (f)

The major product of the Friedel crafts alkylation using the given alkyl chloride is shown below.

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