Chapter 18: Q47P (page 914)
What product is obtained from the reaction of excess benzene with each of the following reagents?
- isobutyl chloride + AICl3
- 1-chloro-2,2-dimethylpropane + AICl3
- dichloromethane + AICl3
Chapter 18: Q47P (page 914)
What product is obtained from the reaction of excess benzene with each of the following reagents?
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Question: How can you prepare the following compounds with benzene as one of the starting materials?
a.)
b.)
c.)
d.)
Draw resonance contributors for the carbanion that would be formed if meta-chloronitrobenzene were to react with hydroxide ion. Why doesn’t the reaction occur?
An aromatic hydrocarbon with a molecular formula of C13H20has an 1H NMR spectrum with a signal at ~7 ppm that integrates to 5H. It also has two singlets; one of the singlets has 1.5 times the area of the second. What is the structure of the aromatic hydrocarbon?
Question: Show how Novocain, a painkiller used frequently by dentists, can be prepared from benzene and compounds containing no more than four carbons.
Novocain
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