Chapter 15: Q73P (page 735)
When treated with an equivalent of methanol, compound A, with the molecular formula C4H6Cl2O, forms the compound whose 1H NMR spectrum is shown here. Identify compound A.
Short Answer
Mechanism followed as:
Chapter 15: Q73P (page 735)
When treated with an equivalent of methanol, compound A, with the molecular formula C4H6Cl2O, forms the compound whose 1H NMR spectrum is shown here. Identify compound A.
Mechanism followed as:
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Get started for freeWhat is the product of an acyl substitution reaction—a new carboxylic acid derivative, a mixture of two carboxylic acid derivatives, or no reaction—if the new group in the tetrahedral intermediate is the following?
a. a stronger base than the substituent that is attached to the acyl group
b. a weaker base than the substituent that is attached to the acyl group
c. similar in basicity to the substituent that is attached to the acyl group
If propionyl chloride is added to one equivalent of methylamine, only a 50% yield of N-methylpropanamide is obtained. If, however, the acyl chloride is added to two equivalents of methylamine, the yield of N-methylpropanamide is almost 100%. Explain these observations.
Why, in the last step of the mechanism for hydroxide-ion promoted hydrolysis of an amide, is the amide ion protonated?
Two products, A and B, are obtained from the reaction of 1-bromobutane with NH3 . Compound A reacts with acetyl chloride to form C, and compound B reacts with acetyl chloride to form D. The IR spectra of C and D are shown. Identify A, B, C, and D.
Propose a mechanism for the reaction of an acyl chloride with acetate ion to form an acid anhydride
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