Chapter 1: Q59P (page 2)
Draw the skeletal structure for each of the compounds
1. CH3CHO
2. CH3OCH3
3. CH3COOH
Chapter 1: Q59P (page 2)
Draw the skeletal structure for each of the compounds
1. CH3CHO
2. CH3OCH3
3. CH3COOH
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Get started for freeDraw the following orbitals:
a. 3sorbital
b. 4sorbitalc.
c. 3porbital
Question:PLP can catalyze both \(\alpha ,\beta - \)-elimination reactions (Problem 33) and \(\beta ,\gamma - \)-elimination reactions. Propose a mechanism for the following PLP-catalyzed
\(\beta ,\gamma - \) elimination reaction:
Predict whether He2+ exist?
Rank the carbanions shown in the margin from most basic to least basic.
HC=C-
H2C=CH-
H3C-CH2-
Calculate the percentages of α-d-glucose and β-d-glucose present at equilibrium from the specific rotations of α-d-glucose, β-d-glucose, and the equilibrium mixture. Compare your values with those given in Section 20.10. (Hint:The specific rotation of the mixture equals the specific rotation of α-d-glucose times the fraction of glucose present in the α-form plus the specific rotation of β-d-glucose times the fraction of glucose present in the β-form.)
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