Chapter 9: Q78P (page 451)
Draw the products obtained from the solvolysis of each of the following compounds in ethanol:
Short Answer
a)
b)
c)
Chapter 9: Q78P (page 451)
Draw the products obtained from the solvolysis of each of the following compounds in ethanol:
a)
b)
c)
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Get started for freea. Which is a stronger base: RO- or RS-?
b. Which is a better nucleophile in an aqueous solution?
c. Which is a better nucleophile in DMSO?
How does the ratio of substitution product to elimination product formed from the reaction of propyl Bromide with CH3O- in methanol change if the nucleophile is changed to CH3S-?
For the pairs of compounds in Problem 48, which is more reactive in an SN2 reaction?
a. Draw the structures of the products obtained from the reaction of each enantiomer of cis-1-chloro-2-isopropylcyclopentane with sodium methoxide in methanol.
b. Are all the products optically active?
c. How would the products differ if the starting material were the trans isomer? Are these products optically active?
d. Will the cis enantiomers or the trans enantiomers form substitution products more rapidly?
e. Will the cis enantiomers or the trans enantiomers form elimination products more rapidly?
Predict the product for the following reaction and write a mechanism to explain how it is formed.
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