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Chapter 27: Q24P (page 1211)

Draw the product of each of the following reactions:

Short Answer

Expert verified

(a)

(b)

(c)

(d)

Step by step solution

01

Under thermal condition

Under thermal conditionthe TE-AC rule will be applied that it is thermal and odd numberedso, the rotation has to be dis-rotatory. So both the groups comes one side and the product will be cis in nature.

02

Under thermal condition

Under thermal condition, the same rule will be applied that is thermal odd numberedand it should be dis-rotatory but during the dis-rotation one group will go up and the another will go down and the product will be appear with the mirror image.

03

Under photo chemical condition

Under photochemical conditionapplying the rule. It is photochemical even numbered and it should be dis-rotatory. Then the product will be appear.

04

Under photo chemical condition

Under photochemical condition, it is photochemical odd numbered and it has to be con-rotatory. So the product will be:

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Bakelite, a durable plastic used for the casing of early radios and TVs, was the first of the thermosetting polymers. It is a highly cross-linked polymer formed from the acid-catalyzed polymerization of phenol and formaldehyde. Because it is much darker than Melmac, Bakelite’s range of colors is limited. Propose a structure for Bakelite.

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