Using the D, A, and D/A designations in Problem 3, indicate how base pairing would be affected if the bases existed in the enol form

Short Answer

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Purine based heterocyclic bases

Pyrimidine based heterocyclic bases

Step by step solution

01

Base pairings

The base pairing is dictated by hydrogen bonding.Adenine forms two hydrogen bonds with thymine but would form only one hydrogen bond with cytosine. Guanine forms three hydrogen bonds with cytosine but would form only one hydrogen bond with thymine.

02

Base pairing in the enol form

If the bases existed in enol form, the hydroxyl group and amine group could act either as hydrogen bond acceptors (A), as hydrogen bond donors (D) ot both A/D.

Hydrogen bonds that can form between enol form bases are one between thymine and adenine and two between cytosine and guanine. Thus, base pairing will be affected if the base existed in the enol form.

Purine based heterocyclic bases

Pyrimidine based heterocyclic bases

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