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Chapter 6: Q55P (page 282)

What is the major product of each of the following reactions?

Short Answer

Expert verified

Here we have to draw the product of each reaction:

Step by step solution

01

How the reaction proceed

In this markoniv addition takes place.

Markoniv addition= Positive ion will go to that double bonded carbon which has more no of hydrogens attached and negative ion will go towards that carbon which has less number of hydrogens attached.

Methyl shift= Here in these reactions methyl shift also takes place. When the carbocation formed then to stable the carbocation methyl changes its place and form the carbocation more stable.

02

Final answer

The product of each reaction:

a) Markoniv addition takes place.

b) Markoniv addition takes place.

c) Methyl shift takes place and Br will attack on positive charge and attach with it.

d) Methyl shift takes place and Br will attack on positive charge and attach with it.

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Most popular questions from this chapter

eDraw structures for the following:

a. 2-propyloxirane

b. cyclohexene oxide

c. 2,2,3,3-tetramethyloxirane

d. 2,3-epoxy-2-methylpentane

What is the product of the addition of I-Cl to 1-butene? (Hint: Chlorine is more electronegative than iodine [Table 1.3].)

Explain why 3-methylcyclohexene should notbe used as the starting material in Problem 52b.

What will be the major product of the reaction of 2-methyl-2-butene with each of the following reagents?

a. HBr

b. HI

c. Cl2/CH2Cl2

d. O3, −78 °C, followed by (CH3)2S

e. H2/Pd

f. MCPBA (a peroxyacid)

g. H2O + H2SO4

h. Br2/CH2Cl2

i. Br2/H2O

j. Br2/CH3OH

k. BH3/THF, followed by H2O2, HO-, H2O

Propose a mechanism for the following reaction:
See all solutions

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