Chapter 6: Q73P (page 284)
Which compound has the greater dipole moment?
Chapter 6: Q73P (page 284)
Which compound has the greater dipole moment?
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Get started for freeWhen fumarate reacts with D2O in the presence of the enzyme fumarase, only one isomer of the product is formed, as shown here. Is the enzyme catalyzing a syn or an anti-addition of D2O?
What stereoisomers would you expect to obtain from each of the following reactions
Show how each of the following compounds can be synthesized from an alkene:
The second-order rate constant (in units of M-1 s-1) for acid-catalysed hydration at 25 °C is given for each of the following alkenes:
a. Calculate the relative rates of hydration of the alkenes. (Hint: Divide each rate constant by the smallest rate constant of the series: 3.51 × 10-8.)
b. Why does (Z)-2-butene react faster than (E)-2-butene?
c. Why does 2-methyl-2-butene react faster than (Z)-2-butene?
d. Why does 2,3-dimethyl-2-butene react faster than 2-methyl-2-butene?
Each of the following reactions has two nucleophiles that could add to the intermediate formed by the reaction of the alkene with an electrophile. What is the major product of each reaction
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