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Chapter 17: Q17-39E (page 567)

Which of the eight alcohols that you identified in Problem 17-38 react with ${CrO}_{3}$ in aqueous acid? Show the products you would expect from each reaction

Short Answer

Expert verified

The reaction followed as:

Step by step solution

01

Reaction with chromic acid

Chromic acid is the reagent used for the reduction of the alcohol to carboxylic acid, aldehyde and ketone.

02

Isomer ofC5H12O

Isomers of $C_{5} H_{12} O$ given below as u see are the compound have same molecular formula the only difference is in their structure that is by changing the position of hydroxy group and by branching the carbon chain as shown:

03

Reaction of the isomer with chromic acid

Chromic acid convert primary alcohol into carboxylic acid and secondary alcohol into ketone and tertiary do not now show reaction like isomer 2methyl2 butanol as shown:

Reaction of Isomers

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Most popular questions from this chapter

Question: Give IUPAC names for the following compounds:

What products would you obtain from reaction of 1-pentanol with the

following reagents?

(a) ${PBr}_{3}$

(b) ${SOCl}_{2}$

(c) ${CrO}_{3}$ , $H_{2} O$ , $H_{2} {SO}_{4}$

(d) Dess–Martin periodinane

Question:The conversion of 3° alcohols into alkenes under acidic conditions involves two cationic intermediates. For each reaction, draw the complete mechanism using curved arrows.

a)

b)

c)

Epoxides react with Grignard reagents to yield alcohols. Propose a mechanism.

p-Nitrobenzyl alcohol is more acidic than benzyl alcohol, but p-methoxy-benzyl alcohol is less acidic. Explain.

See all solutions

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