Chapter 17: Q2P (page 528)
Draw structures corresponding to the following IUPAC names:
- (Z)-2-Ethyl-2-buten-1-ol
- 3-Cyclohexen-1-ol
- trans-3-Chlorocycloheptanol
- 1,4-Pentanediol
- 2,6-Dimethylphenol
- o-(2-Hydroxyethyl)phenol
Short Answer
Answer
Chapter 17: Q2P (page 528)
Draw structures corresponding to the following IUPAC names:
Answer
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Get started for freeQuestion:When the alcohol below is treated with and pyridine, the expected elimination product is formed. However, when the same alcohol is treated with , the elimination product is 1,2-dimethylcyclopentene. Propose a mechanism for each pathway to account for these differences.
Question:Identify the type of substitution mechanism ,involved in the conversion of the alcohol shown into the corresponding alkyl halide.
a.
b)
c)
A problem often encountered in the oxidation of primary alcohols to acids is that esters are sometimes produced as by-products. For example, oxidation of ethanol yields acetic acid and ethyl acetate:
Propose a mechanism to account for the formation of ethyl acetate. Take into account the reversible reaction between aldehydes and alcohols:
Question:When the alcohol below is treated with and pyridine, the expected elimination product is formed. However, when the same alcohol is treated with , the elimination product is 1,2-dimethylcyclopentene. Propose a mechanism for each pathway to account for these differences.
Give IUPAC names for the following compounds:
(a)
(b)
(c)
(d)
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