Chapter 19: Q12P (page 624)
Draw the following molecule as a skeletal structure, and show how it can be prepared from a ketone and an amine.
Short Answer
N, N-diethylcylopent-1en-1-amine
Formation of N, N-diethylcyclopent-1-enamine
Chapter 19: Q12P (page 624)
Draw the following molecule as a skeletal structure, and show how it can be prepared from a ketone and an amine.
N, N-diethylcylopent-1en-1-amine
Formation of N, N-diethylcyclopent-1-enamine
All the tools & learning materials you need for study success - in one app.
Get started for freeWhat is the stereochemistry of the pyruvate reduction shown in Figure 19-12? Does NADH lose its pro-R or pro-S hydrogen? Does addition occur to the Si face or Re face of pyruvate? (Review Section 5-11.)
Cyclohexanone forms a cyanohydrin in good yield but 2,2,6-trimethylcyclohexanonedoes not. Explain.
Draw structures corresponding to the following names:
(a) 3-Methylbutanal (b) 4-Chloro-2-pentanone
(c) Phenylacetaldehyde (d) cis-3-tert-Butylcyclohexanecarbaldehyde
(e) 3-Methyl-3-butenal (f) 2-(1-Chloroethyl)-5-methylheptanal
Paraldehyde, a sedative, and hypnotic agent, is prepared by treatment of acetaldehyde with an acidic catalyst. Propose a mechanism for the reaction.
The enamine prepared from acetone and dimethylamine is shown in its
lowest-energy form.
(a) What is the geometry and hybridization of the nitrogen atom?
(b) What orbital on nitrogen holds the lone pair of electrons?
(c) What is the geometric relationship between the p orbitals of the
double bond and the nitrogen orbital that holds the lone pair? Why
do you think this geometry represents the minimum energy?
What do you think about this solution?
We value your feedback to improve our textbook solutions.