Chapter 19: Q19-10P (page 624)
Show the products you would obtain by acid-catalyzed reaction of cyclohexanonewith ethylamine, CH3CH2NH2, and with diethylamine, (CH3CH2)2NH.
Chapter 19: Q19-10P (page 624)
Show the products you would obtain by acid-catalyzed reaction of cyclohexanonewith ethylamine, CH3CH2NH2, and with diethylamine, (CH3CH2)2NH.
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Get started for freeIt is not uncommon for organic chemists to prepare acetals by an exchange-type process known as transacetalization. Predict the product(s) and show the mechanism for the transacetalization reactions below.
a.
b.
Identify the carbonyl compound and the alcohol that were used to prepare the following acetal:
Propose structures for ketones or aldehydes that have the following \(^1H\;NMR\) spectra:
(a) \({C_{10}}{H_{12}}O\)
IR: 1710 \(c{m^{ - 1}}\)
(b)\({C_6}{H_{12}}{O_3}\)
IR: 1715\(c{m^{ - 1}}\)
p-Nitrobenzaldehyde is more reactive toward nucleophilic additions than p-methoxybenzaldehyde. Explain.
Draw structures corresponding to the following names:
(a) 3-Methylbutanal (b) 4-Chloro-2-pentanone
(c) Phenylacetaldehyde (d) cis-3-tert-Butylcyclohexanecarbaldehyde
(e) 3-Methyl-3-butenal (f) 2-(1-Chloroethyl)-5-methylheptanal
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