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Chapter 9: Q. 9-9-3 P-a (page 265)

What products would you expect from the following reactions?

a. CH3CH2CH2C≡CH+Cl2

Short Answer

Expert verified

a.

Step by step solution

01

Markovnikov reactions

In this the alkyne is converted to alkene by the halogenation that the three out of one triple bond is break foe the addition of halogen but the halogen are added always in trans geometry.

02

Reaction of alkyne with halide CH3CH2CH2C≡CH+Cl2

When alkyne reacts with halide they undergo an additional reaction to form a halogen-substituted alkene. Alkyne follows Markovnikov regiochemistry in which two added halogen atoms are always in a trans relationship with each other as shown:

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Most popular questions from this chapter

Question: How would you carry out the following reactions?

Show the terminal alkyne and alkyl halide from which the following products can be obtained. If two routes look feasible, list both.

b.(CH3)2CHC≡CCH2CH3

Propose structures for hydrocarbons that give the following products

on oxidative cleavage by KMnO4 or O3 :

Which of the following bases could be used to deprotonate 1-butyne?

(b)

Let be a group and assume that for each positive integer i , Ni is a normal subgroup of G. If every element of can be written uniquely in the form ni1 .ni2 ...nikwith i1 < i2 < ... < ik and nij∈Nij , prove that G≅∑i=1 Ni (see Exercise 34). [Hint: Adapt the proof of Theorem 9.1 by defining f(a1, a2...) to be the product of those ai that are not the identity element.]
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