Chapter 15: Q 15-15-18 E-a (page 477)
Give IUPAC names for the following compounds
a)
Short Answer
a)
5-methyl-2-phenylhexane
Chapter 15: Q 15-15-18 E-a (page 477)
Give IUPAC names for the following compounds
a)
a)
5-methyl-2-phenylhexane
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Get started for freeAromatic substitution reactions occur by the addition of an electrophile such as to an aromatic ring to yield an allylic carbocation intermediate, followed by loss of . Show the structure of the intermediate formed by the reaction of benzene with .
To be aromatic, a molecule must have 4n+2 p electrons and must have a planar, monocyclic system of conjugation. Cyclodecapentaene fulfills one of these criteria but not the other and has resisted all attempts at synthesis. Explain.
Cyclooctatetraene readily reacts with potassium metal to form the stable cyclooctatetraene dianion, . Why do you suppose this reaction occurs so easily? What geometry do you expect for the cyclooctatetraene dianion?
How many electrons does each of the four nitrogen atoms in purine contribute to the aromatic system?
Draw structures corresponding to the following names:
(a) 3-Methyl-1,2-benzenediamine
(b) 1,3,5-Benzenetriol
(c) 3-Methyl-2-phenylhexane
(d) o-Aminobenzoic acid
(e) m-Bromophenol
(f) 2,4,6-Trinitrophenol (picric acid)
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