Chapter 15: Q15-13E (page 477)
Give IUPAC names for the following substances (red 5 O, blue 5 N):
Short Answer
- m-isopropyl phenol
- o-nitrobenzoic acid
Chapter 15: Q15-13E (page 477)
Give IUPAC names for the following substances (red 5 O, blue 5 N):
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Get started for freeN-Phenylsydnone, so-named because it was first studied at the University of Sydney, Australia, behaves like a typical aromatic molecule. Explain, using the Hückel’s rule .
N-phenylsydnone
Draw structures corresponding to the following names:
(a) 3-Methyl-1,2-benzenediamine
(b) 1,3,5-Benzenetriol
(c) 3-Methyl-2-phenylhexane
(d) o-Aminobenzoic acid
(e) m-Bromophenol
(f) 2,4,6-Trinitrophenol (picric acid)
Draw an energy diagram for the three molecular orbitals of the cyclopropenyl system(C3H3). How are these three molecular orbitals occupied in the cyclopropenyl anion, cation, and radical? Which of the three substances is aromatic according to Hückel’s rule?
Draw structures corresponding to the following names:
(a) 3-Methyl-1,2-benzenediamine
(b) 1,3,5-Benzenetriol
(c) 3-Methyl-2-phenylhexane
(d) o-Aminobenzoic acid
(e) m-Bromophenol
(f) 2,4,6-Trinitrophenol (picric acid)
Indole is an aromatic heterocycle that has a benzene ring fused to a pyrrole ring. Draw an orbital picture of indole.
(a) How many p electrons does indole have?
(b) What is the electronic relationship of indole to naphthalene?
Indole
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