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Chapter 23: Q23-13P (page 768)

What product would you expect from the following mixed Claisen-like reaction?

Short Answer

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The product from the above reactants when they undergo a mixed Claisen-like reaction are acetate and alcohol.

Step by step solution

Concept

A mixed Claisen reaction is effective when only one of the two partners has an acidic α- hydrogen atom and the other does not.

therefore, one form of acetate can convert into an enolate ion hence one is a donor and another is an accepter.

Chemical reaction occurs (Mixed Claisen reaction):

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Most popular questions from this chapter

The Stork enamine reaction and the intramolecular aldol reaction can be carried out in sequence to allow the synthesis of cyclohexanones. For example, the reaction of the pyrrolidine enamine of cyclohexanone with 3-buten-2-one, followed by enamine hydrolysis and base treatment, yields the product indicated. Write each step, and show the mechanism of each.