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Chapter 23: Q3P (page 759)

What enone product would you expect from aldol condensation of each of the following compounds?

Short Answer

Expert verified

ENONEcontains α-βunsaturated carbonyl compound having alkene which is conjugated to ketone in the same compound.

Step by step solution

01

(a) first product is:

02

(b) second product is:


03

(c)third product is:

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Most popular questions from this chapter

The major product formed by intramolecular aldol cyclization of 2,5-heptanedione (Problem 23-51) has two singlet absorptions in the 1H NMR spectrum, at 1.65 d and 1.90 d, and has no absorptions in the range 3 to 10 d. What is its structure?

What condensation products would you expect to obtain by treatment of the following substances with sodium ethoxide in ethanol?

(a)Ethyl butanoate

(b)Cycloheptanone

(c)3,7-Nonanedione

(d)3-Phenylpropanal

What product would you expect from the following mixed Claisen-like reaction?

How could you prepare the following cyclohexanones by combining a Stork enamine reaction with an intramolecular aldol condensation? (See Problem 23-64.)

How would you prepare the following compound using a Robinson annulation reaction between a𝛃-diketone and an𝛂,𝛃 -unsaturated ketone? Draw the structures of both reactants and the intermediate Michael addition product
See all solutions

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