Chapter 21: Q54 E (page 726)

The Following reactivity order has been found for the saponification of alkyl acetates by aqueous NaOH Explain.
$C H_{3} C O_{2} C H_{3} > C H_{3} C O_{2} C H_{2} C H_{3} > C H_{3} C O_{2} C H {(C H_{3})}_{2} > C H_{3} C O_{2} C H {(C H_{3})}_{3}$

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The Order of saponification is

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The order of saponification Reaction of Ethyl acetate with sodium hydroxide (Saponification)

The Reaction for the saponification of an ester using aqueousNaOH is

To Structure the given issues of ester

The Structures of the given issues of ester, that all other things removing constant. Therefore, there is only an increase in the steric bulk of the leaving group

Increases the electron density on the carbonyl carbon

That is from greater numbers of ${CH}_{3}$ groups attached, the mesomeric electron release ofdata-custom-editor="chemistry" ${CH}_{3}$ increases electron density on the carbonyl carbon

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The Following reactivity order has been found for the saponification of alkyl acetates by aqueous NaOH Explain.
$C H_{3} C O_{2} C H_{3} > C H_{3} C O_{2} C H_{2} C H_{3} > C H_{3} C O_{2} C H {(C H_{3})}_{2} > C H_{3} C O_{2} C H {(C H_{3})}_{3}$

Short Answer

Step by step solution

The order of saponification Reaction of Ethyl acetate with sodium hydroxide (Saponification)

To Structure the given issues of ester

Increases the electron density on the carbonyl carbon

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The Following reactivity order has been found for the saponification of alkyl acetates by aqueous NaOH Explain. CH3CO2CH3>CH3CO2CH2CH3>CH3CO2CHCH32>CH3CO2CHCH33

Short Answer

Step by step solution

The order of saponification Reaction of Ethyl acetate with sodium hydroxide (Saponification)

To Structure the given issues of ester

Increases the electron density on the carbonyl carbon

One App. One Place for Learning.

Most popular questions from this chapter

Recommended explanations on Chemistry Textbooks

The Earths Atmosphere

Organic Chemistry

Physical Chemistry

Chemical Reactions

Chemistry Branches

Nuclear Chemistry

Study anywhere. Anytime. Across all devices.

The Following reactivity order has been found for the saponification of alkyl acetates by aqueous NaOH Explain.
$C H_{3} C O_{2} C H_{3} > C H_{3} C O_{2} C H_{2} C H_{3} > C H_{3} C O_{2} C H {(C H_{3})}_{2} > C H_{3} C O_{2} C H {(C H_{3})}_{3}$