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Chapter 21: Q78E (page 726)

Assign structures to compounds with the following 1H NMR spectra:

(a)C5H9ClO2

IR:1735 cm-1

Short Answer

Expert verified

Thestructure of the compound using 1H NMR spectra can be drawn.

Step by step solution

01

Drawing the structure for C5H9ClO2with IR=1735 cm-1

The structure can be drawn as,

02

Drawing the structure for C7H12O4with IR=1735 cm-1

The IR bond frequency indicates dicarboxylic acid.

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Most popular questions from this chapter

21-73 N,N-Diethyl-m-toluamide (DEET) is the active ingredient in manyinsect repellent preparations. How might you synthesize this substancefrom m-bromotoluene?

21-46 Draw structures corresponding to the following names

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21-36 When 4-dimethylaminopyridine (DMAP) is added in catalytic amountsto acetic anhydride and an alcohol, it significantly increases the rate of ester formation. The process begins with a reaction between acetic anhydride and DMAP to form a highly reactive acetylpyridinium intermediate that is more reactive than acetic anhydride itself. Propose a mechanism for this process that includes the formation and reaction of the acetylpyridinium intermediate.

Propose structures for compounds that have the following formulas and IR absorptions:

(a) C6H12O2, 1735 cm-1

(b) C4H9NO, 1650 cm-1

(c) C4H5ClO, 1780 cm-1
See all solutions

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