Chapter 14: 25Eb (page 447)
Give IUPAC names for the following compounds:
Short Answer
Hepta-1,3,5-triene
Chapter 14: 25Eb (page 447)
Give IUPAC names for the following compounds:
Hepta-1,3,5-triene
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Get started for freeShow the structures of all possible adducts of the following diene with1 equivalent of HCl:
The following ultraviolet absorption maxima have been measured:
1,3-Butadiene 217 nm
2-Methyl-1,3-butadiene 220 nm
1,3-Pentadiene 223 nm
2,3-Dimethyl-1,3-butadiene 226 nm
2,4-Hexadiene227 nm
2,4-Dimethyl-1,3-pentadiene 232 nm
2,5-Dimethyl-2,4-hexadiene 240 nm
What conclusion can you draw about the effect of alkyl substitution on
UV absorption maxima? Approximately what effect does each added
alkyl group have?
Would you expect a conjugated diyne such as 1,3-butadiyne to undergo Diels-Alder reaction with a dienophile? Explain.
Luminol, which is used by forensic scientists to find blood, fluoresces as a result of Diels-Alder like process. The dianion of luminal reacts with to form an unstable peroxide intermediate that then loses nitrogen to form a dicarboxylate and emit light. The process is similar to that in 14-21 and 14-22. Propose a mechanism for this process.
Give IUPAC names for the following compounds:
(a)
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