Chapter 14: 33E (page 447)
Show the structure, including stereochemistry, of the product from the following Diels-Alder reaction:
Chapter 14: 33E (page 447)
Show the structure, including stereochemistry, of the product from the following Diels-Alder reaction:
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Get started for freeGive IUPAC names for the following compounds:
Arrange the molecules according to where you would expect to find
their wavelength of maximum absorption in UV spectroscopy, from shortest to longest wavelength.
a)
b)
c)
How could you use Diels-Alder reactions to prepare the following products ? Show the starting diene and dienophile in each case.
c)
Dimethyl butynedioate also undergoes a Diel-Alder reaction with (2E, 4Z)-2,4-hexadiene, but the stereochemistry of the product is different from that of the (2E,4E) isomer (Problem 14-62). Explain.
Luminol, which is used by forensic scientists to find blood, fluoresces as a result of Diels-Alder like process. The dianion of luminal reacts with to form an unstable peroxide intermediate that then loses nitrogen to form a dicarboxylate and emit light. The process is similar to that in 14-21 and 14-22. Propose a mechanism for this process.
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