Chapter 18: Q27E (page 594)
Predict the product(s) and provide the mechanism for each reaction below. What do the mechanisms have in common?
a.
b.
c.
d.
Short Answer
a.
b.
c.
d.
Chapter 18: Q27E (page 594)
Predict the product(s) and provide the mechanism for each reaction below. What do the mechanisms have in common?
a.
b.
c.
d.
a.
b.
c.
d.
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Get started for freeThe red fox (Vulpesvulpes) uses a chemical communication system based on scent marks in urine. One component of fox urine is a sulfide whose mass spectrum has . IR spectroscopy shows an intense band at and NMR spectroscopy reveals the following peaks:
(, singlet); (, singlet); (, triplet, ); (, triplet, ); (, broad). Propose a structure consistent with these data. [Note: absorbs at ].Why are HI and HBr more effective than HCl in cleaving ethers? (See Section 11-3).
Write the mechanism of the acid-induced cleavage of tert-butyl cyclohexyl ether to yield cyclohexanol and 2-methylpropene.
Name the following ethers:
c)
Methyl aryl ethers, such as anisole, are cleaved to iodomethane and aphenoxide ion by treatment with LiI in hot DMF. Propose a mechanismfor this reaction.
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