Chapter 8: Q8-56 E (page 262)
Poly (vinyl pyrrolidone), prepared from N-vinylpyrrolidone, is used in cosmetics and as a synthetic substitute for blood. Draw a representative segment of the polymer.
Short Answer
Answer
Chapter 8: Q8-56 E (page 262)
Poly (vinyl pyrrolidone), prepared from N-vinylpyrrolidone, is used in cosmetics and as a synthetic substitute for blood. Draw a representative segment of the polymer.
Answer
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Get started for freeIodine azide,adds to alkenes by an electrophilic mechanism similar to that of bromine. If a monosubstituted alkene such as1-butene isused, only one product results:
b) Calculate formal charges for the atoms in both resonance structuresyou drew for,in part (a).
How many alkene products, including E, Z isomers, might be obtained by dehydration of 3-methyl-3-hexanol with aqueous sulfuric acid?
Question: In planning the synthesis of one compound from another, it’s just as important to know what not to do as to know what to do. The following reactions all have serious drawbacks to them. Explain the potential problems of each.
Iodine azide, adds to alkenes by an electrophilic mechanism similar to that of bromine. If a monosubstituted alkene such as 1-butene isused, only one product results:
a) Add lone-pair electrons to the structure shown for, and draw a
second resonance form for the molecule.
Compound A has the formula . It reacts rapidly with to give and a carboxylic acid, B , but reacts with only 1 molar equivalent of on catalytic hydrogenation over a palladium catalyst. On hydrogenation under conditions that reduce aromatic rings, 4 equivalents of are taken up and hydrocarbon C is produced. What are the structures of A, B, and C? Write the reactions.
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