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Chapter 11: Q.11-50c (page 350)

Question:What products would you expect from the reaction of 1-bromopropane with each of the following?

(c) NaI

Short Answer

Expert verified

Answer

CH3CH2CH2Br+Nal→CH3CH2CH2l+NaBrSubstitutionreaction

Step by step solution

01

SN2 reaction

It is a nucleophilic substitution reaction in which an old bond is broken, and a new bond is formed. Both processes co-occur. Hence, it’s a single-step reaction.

Two reacting species are involved in the rate-determining steps.

02

Reaction of CH3CH2CH2Br+Nal

It is a substitution reaction in which C-Br is broken, and the C-I bond is formed in a single-step process, which means the iodide ion substitutes for the bromide ion. Hence, a substitution reaction and bromide and iodide are nucleophiles’ so-called nucleophilic substitution reactions.

CH3CH2CH2Br+Nal→CH3CH2CH2l+NaBrSubstitutionreaction

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Most popular questions from this chapter

How might you prepare each of the following molecules using a nucleophilic substitution reaction at some step?

d.CH3CH2CH2CH2NH2

Rank the following substances in order of their expected SN1reactivity:

Which reaction in each of the following pairs would you expect to be faster?

(d) Thedisplacement byon bromomethane in benzene or in acetonitrile

Question: 1-Chloro-1,2-diphenylethane can undergo E2 elimination to give either cis- or trans-1,2-diphenylethylene (stilbene). Draw Newman projections of the reactive conformations leading to both possible products, and suggest a reason why the trans alkene is the major product.

Question:What products would you expect from the reaction of 1-bromopropane with each of the following?

(d) NaCN

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